| Autor: |
Hong-Tao Li, Rui-Ning Yang, Tao Liu, Fei Xie, Hao-Jie Duan, Dan-Dan Xia, Hao Zhou, Zhong-Tao Ding |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
Phytochemistry. 205:113475 |
| ISSN: |
0031-9422 |
| DOI: |
10.1016/j.phytochem.2022.113475 |
| Popis: |
Five unprecedented polyketide metabolites were isolated and characterized from a rhizospheric soil-derived Penicillium sp. YUD17004. Their diverse structures included two indanone-type polyketides penicillyketides A and B, a phthalide-like polyketides penicillyketide C, a symmetrical chromone dimer penicillyketide D, along with a pyrone derivative pyranlyketide, which were elucidated by spectroscopic data interpretation and quantum chemical electronic circular dichroism calculation. Notably, the structures of penicillyketides A and B feature a highly functionalized indanone ring nucleus, but differ from other indanone-containing polyketides by the alkyl substitution pattern. The structure of penicillyketide C comprises a furanone ring instead of the hydroxycyclopentenone ring characteristic for penicillyketides A and B, and represents an undescribed arrangement within C |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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Full Text from ScienceDirect