Can Manganese(III)-Iodosylarene Act as an Oxidant Alongside High-Valent Manganese(V)-Oxo Complexes?
| Autor: | Chungu Xia, Yiran Kang, Fabián G. Cantú Reinhard, Yong Wang, Sam P. de Visser, Fang Wang |
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| Rok vydání: | 2018 |
| Předmět: |
chemistry
010405 organic chemistry Manchester Institute of Biotechnology chemistry.chemical_element Reactivity (chemistry) General Chemistry Manganese ResearchInstitutes_Networks_Beacons/manchester_institute_of_biotechnology 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences |
| Zdroj: | Kang, Y, Wang, F, Cantu Reinhard, F, Chungu, X & De Visser, S 2018, ' Can Manganese(III)-Iodosylarene Act as an Oxidant Alongside High-Valent Manganese(V)-Oxo Complexes? ', Chemistry Select . https://doi.org/10.1002/slct.201800678 |
| ISSN: | 2365-6549 |
| Popis: | Metalloenzymes often utilize a high-valent metal-oxo species in their catalytic cycle that is formed through a combination of reduction/proton transfer steps from O2. In biomimetic chemistry, by contrast, iodosylarenes are commonly used as terminal oxidants to generate these high valent metal-oxo intermediates. There has been controversy in the literature for many years, whether the iodosylarene (or one of its side-products in a reaction with a metal center) can act as an active oxidant. Herein, we present a comprehensive theoretical study on the thioanisole oxidation by a range of possible oxidants originating from a reaction mixture of a Mn(III) complex with iodosylbenzene. We show here, for the first time, that actually iodosylarene complexes can react with substrates themselves and hence are active oxidants. In particular, the [MnIII(PhIO)], [MnV(O)(PhIO)] and [MnIV(O)-I(Ph)-O•] complexes react with substrate via low energy oxygen atom transfer reactions |
| Databáze: | OpenAIRE |
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