Study of the ternary system Al–H– RE ( RE = Er, La and Y) in liquid state
| Autor: | Michel Latroche, Jean-Marc Joubert, Jocelyn Prigent |
|---|---|
| Přispěvatelé: | Institut de Chimie et des Matériaux Paris-Est (ICMPE), Institut de Chimie du CNRS (INC)-Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), Constellium Technology Center (C-TEC), Université Paris-Est Créteil Val-de-Marne - Paris 12 (UPEC UP12)-Centre National de la Recherche Scientifique (CNRS), Constellium CRV, CRV Voreppe |
| Rok vydání: | 2017 |
| Předmět: |
Work (thermodynamics)
Hydrogen Energy Engineering and Power Technology chemistry.chemical_element Thermodynamics 02 engineering and technology 01 natural sciences 7. Clean energy 020501 mining & metallurgy Metal Aluminium 0103 physical sciences Solubility CALPHAD ComputingMilieux_MISCELLANEOUS Phase diagram 010302 applied physics Ternary numeral system Renewable Energy Sustainability and the Environment Chemistry [CHIM.MATE]Chemical Sciences/Material chemistry Condensed Matter Physics Fuel Technology 0205 materials engineering visual_art visual_art.visual_art_medium |
| Zdroj: | International Journal of Hydrogen Energy International Journal of Hydrogen Energy, Elsevier, 2017, 42 (35), pp.22348-22352. ⟨10.1016/j.ijhydene.2017.01.002⟩ |
| ISSN: | 0360-3199 |
| DOI: | 10.1016/j.ijhydene.2017.01.002 |
| Popis: | Hydrogen is the only gas able to dissolve in aluminum. The solubility S of hydrogen in Al obeys the Sieverts' law and S is much larger in the liquid phase (above 660.4 °C) than in the solid one. This might lead to the formation of porosity during aluminum casting. In the present work, the ternary system Al–H– RE ( RE = Er, La, Y) is investigated. The equilibria between the different phases are determined in the presence of liquid Al, RE and H 2 gas by both experimental measurements and phase diagram calculations. The possible formation of metallic hydrides and the change in the hydrogen solubility S are discussed regarding pressure and temperature determining the thermodynamics of the system. |
| Databáze: | OpenAIRE |
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