Cleavage of Carbon Disulfide by n ‐Propyldiphenylphosphine and Nickel(II) Bromide

Autor:	Alan L. Balch, Lauren A. deGuzman, Michael M. Aristov, Xian B. Powers, Marilyn M. Olmstead
Rok vydání:	2019
Předmět:	Carbon disulfide Carbon atom 010405 organic chemistry Chemistry Nickel(II) bromide Organic Chemistry chemistry.chemical_element General Chemistry Bond formation 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound Nickel Bromide X-ray crystallography Molecule
Zdroj:	Chemistry – A European Journal. 25:2491-2496
ISSN:	1521-3765 0947-6539
DOI:	10.1002/chem.201805570
Popis:	Carbon disulfide is cleaved by n-propyldiphenylphosphine and nickel(II) bromide in a one-step process, to form two unprecedented complexes: orange, [Ni(S2 C2 (Pn PrPh2 )2 )Br(Pn PrPh2 )]Br⋅CS2 (1) and purple [Ni{η2 -SC(Pn PrPh2 )2 }Br(Pn PrPh2 )]Br⋅0.5CS2 (2). Orange (1) contains a dithiolene-related ligand that results from carbon-carbon bond formation, while purple (2) contains a remarkable ligand in which two n-propyldiphenylphosphine molecules have added to a carbon atom of a CS unit that is coordinated to nickel.
Databáze:	OpenAIRE
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