Ball milling synthesis of covalent organic framework as a highly active photocatalyst for degradation of organic contaminants
| Autor: | Zhi Tang, John P. Giesy, Fengchang Wu, Sijing He, Hongyun Niu, Xiaoli Zhao, Hongzhou Lv |
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| Rok vydání: | 2019 |
| Předmět: |
021110 strategic
defence & security studies Environmental Engineering Materials science Health Toxicology and Mutagenesis 0211 other engineering and technologies 02 engineering and technology 010501 environmental sciences 01 natural sciences Pollution Catalysis Solvent Crystallinity chemistry.chemical_compound chemistry Chemical engineering Photocatalysis Environmental Chemistry Phenol Photodegradation Waste Management and Disposal Ball mill 0105 earth and related environmental sciences Covalent organic framework |
| Zdroj: | Journal of Hazardous Materials. 369:494-502 |
| ISSN: | 0304-3894 |
| DOI: | 10.1016/j.jhazmat.2019.02.046 |
| Popis: | Facile, environmentally-friendly fabrication of high-yield and stable covalent organic framework (COF) materials has been a limitation to their large-scale production and application. In this work, ball milling was used to synthesize COF by mechanochemical reaction between 1,3,5-triformylphloroglucinol (Tp) and melamine (MA) at ambient temperature. Different routes (liquid-free, solvent-assisted and catalyst-assisted) and proportions of liquids (solvents or catalyst) were investigated. Two morphologies were obtained when various amounts of liquid were added during grinding. The two forms were interwoven thread-shaped and exfoliative thin ribbon-like structures. Further, visible-light photocatalytic (λ > 400 nm) performance and mechanism of the two structures of COFs were investigated. The exfoliative ribbon-like structures exhibited greater rates of photodegradation of phenol and retained 87.6% of initial photodegradation after being used four times. Addition of liquid catalyst not only improved crystallinity of the COF materials, but also enhanced rates of photocatalytic reactions. Photocatalytic activity of the exfoliative structure of TpMA synthesized by ball milling was comparable with that of the photocatalyst prepared by use of the solvothermal method, while time to prepare the catalyst was shortened by 36-fold and the amount of solvent used was reduced by 8-fold at room temperature. Mechanochemical synthesis is a promising potential tool for large-scale production of COFs, which will make greater use of COFs for degradation of pollutants. |
| Databáze: | OpenAIRE |
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