Study of the refractive index of gasoline+alcohol pseudo-binary mixtures
Autor: | Irina Nita, Olga Iulian, Sibel Osman, Elis Geacai |
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Jazyk: | angličtina |
Rok vydání: | 2017 |
Předmět: |
gasoline
Materials science refractive index alcohol 020209 energy Analytical chemistry Binary number Alcohol 02 engineering and technology predictive equations chemistry.chemical_compound Chemistry 020401 chemical engineering chemistry 0202 electrical engineering electronic engineering information engineering 0204 chemical engineering Gasoline Physics::Chemical Physics mixing rules Refractive index QD1-999 |
Zdroj: | Analele Universităţii "Ovidius" Constanţa: Seria Chimie, Vol 28, Iss 1, Pp 18-24 (2017) |
Popis: | The properties of gasoline change as a result of blending with a bioalcohol, affecting the behavior of the pseudo-binary system. The aim of this paper is to present experimental data of the refractive index for pseudobinary mixtures of a reformate gasoline with ethanol, isopropanol and n-butanol over the entire composition range and for temperature ranging from 293.15 K to 313.15 K. The accuracy of different equations to predict the refractive index of the mixtures was tested. The best prediction accuracy (the lower AAD) corresponded to Eykman and Lorentz-Lorenz mixing rules. A logarithmic equation proposed to correlate the refractive index with composition and temperature of gasoline+alcohol mixtures showed a good accuracy (the absolute average deviation AAD < 0.052%). The deviations in refractive index for investigated systems are negative over the entire composition range and at all investigated temperatures. |
Databáze: | OpenAIRE |
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