Evolution of natural sea surface films: a new quantification formalism based on multidimensional space vector
| Autor: | Katarzyna Boniewicz-Szmyt, Stanislaw J. Pogorzelski |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Normalization (statistics)
Materials science 010504 meteorology & atmospheric sciences Thermodynamic state Surface Properties Health Toxicology and Mutagenesis Mineralogy 010501 environmental sciences 01 natural sciences Viscoelasticity law.invention Cartesian distance classification Natural surfactant films Surface-Active Agents law 2D thermodynamics Pollution monitoring Environmental Chemistry Organic matter Cartesian coordinate system Seawater 0105 earth and related environmental sciences chemistry.chemical_classification General Medicine Pollution chemistry Models Chemical Dimensionless structure vector Snowmelt Thermodynamics Adsorption Adsorptive-viscoelastic rheology Dimensionless quantity Research Article |
| Zdroj: | Environmental Science and Pollution Research International |
| ISSN: | 1614-7499 0944-1344 |
| Popis: | Spatial and temporal variability of natural surfactant sea surface film structural parameters were evaluated from force-area isotherms, film pressure-temperature isochors, dynamic surface tension-time relations performed on samples collected in Baltic Sea shallow coastal waters. The film structure state was postulated as a 10-D dimensionless vector created from the normalized thermodynamic, adsorptive, and viscoelastic film parameters. The normalization procedure is based on the concept of self-corresponding states known in thermodynamics. The values taken by all the reduced parameters indicated a significant deviation from the reference ideal-2D gas behavior. The exhibited deviations of the surface parameters from the background values of the same thermodynamic state of each film were independent on the film-collecting procedure, sample solvent treatment, and temperature. The structural similarity was expressed quantitatively as a (Cartesian, street, and Czebyszew) distance between two vectors of the analyzed film and the standard one from the database, and appeared to be related to environmental conditions, surface-active organic matter production, and migration in the studied coastal sea region. The most distinctive parameters differing the films were y, M w and E isoth, as established from Czebyszew function application. The proposed formalism is of universal concern and could be applied to any natural water surfactant system (seawater, inland water, rain water, and snowmelt water). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink