Oxamic acids: useful precursors of carbamoyl radicals

Autor:	Yannick LANDAIS, Frederic Robert, Gülbin Kurtay, Ogbu Ikechukwu
Rok vydání:	2022
Předmět:	Oxamic Acid Materials Chemistry Metals and Alloys Ceramics and Composites Urea General Chemistry Amides Oxidation-Reduction Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:7593-7607
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc01953a
Popis:	This review article describes the recent development in the chemistry of carbamoyl radicals generated from oxamic acids. This mild and efficient method compares well with previous methods of generation of these nucleophilic radicals. The oxidative decarboxylation of oxamic acids can be mediated through thermal, photochemical, electrochemical or photoelectrochemical means, generating carbamoyl radicals, which may further add to unsaturated systems to provide a broad range of important amides. Oxidative decarboxylation of oxamic acids also offers a straightforward entry for the preparation of urethanes, ureas, and thioureas.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1ef6b3ad4c21b38cb352ad52b03f0d49 https://doi.org/10.1039/d2cc01953a Zobrazit plný text záznamu