Exploring the construction of multicompartmental micelles by halogen bonding of complementary macromolecules
| Autor: | Alan Vanderkooy, Mark S. Taylor |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
inorganic chemicals
Halogen bond Aqueous solution 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Micelle 0104 chemical sciences Solvent chemistry.chemical_compound chemistry Transmission electron microscopy Polymer chemistry Polystyrene Physical and Theoretical Chemistry 0210 nano-technology Derivative (chemistry) Macromolecule |
| Zdroj: | Faraday discussions. 203 |
| ISSN: | 1364-5498 |
| Popis: | An approach to the construction of multicompartmental micelles, using halogen bonding between complementary macromolecules, is described. The design involves a sequential assembly protocol, in which the initial compartments are formed by interpolymer halogen bonding, followed by the collapse of a second, hydrophobic compartment upon transfer to aqueous solvent. Triblock terpolymers incorporating a halogen bond accepting segment have been synthesized. Transmission electron microscopy was used to characterize multicompartmental assemblies generated from these terpolymers in the presence of a halogen bond donor-functionalized polystyrene derivative. |
| Databáze: | OpenAIRE |
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