Aqua(glycinato)(3,4,7,8-tetramethyl-1,10-phenanthroline)copper(II) Nitrate
| Autor: | Angel Alvarez-Larena, Joan F. Piniella, Lena Ruiz-Ramirez, J. L. Briansó-Penalva, Gerardo Ferrer-Sueta, Rafael Moreno-Esparza |
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| Rok vydání: | 1995 |
| Předmět: |
chemistry.chemical_classification
Crystallography Base (chemistry) Stereochemistry Ligand Phenanthroline Cristal·lografia General Medicine Crystal structure Ring (chemistry) General Biochemistry Genetics and Molecular Biology Planarity testing chemistry.chemical_compound chemistry Copper(II) nitrate Molecule |
| Zdroj: | Dipòsit Digital de Documents de la UAB Universitat Autònoma de Barcelona Recercat. Dipósit de la Recerca de Catalunya instname Recercat: Dipósit de la Recerca de Catalunya Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Popis: | In the title compound, [Cu(C 2 H 4 NO 2 )(C 16 H 16 N 2 )(H 2 O)]NO 3 , Cu II displays distorted square-pyramidal coordination where the water molecule is in the apical position and the base is defined by the N and one of the O atoms from the glycinate ligand, and both phenanthroline N atoms. The phenanthroline chelate-ring plane (N1, C12, C11, N2, Cu) is slightly distorted from planarity, whereas the five-membered ring formed by the glycinate ligand (defined by atoms N3, C18, C17, O1 and Cu), presents a distorted half-chair conformation |
| Databáze: | OpenAIRE |
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