Liquid adsorption of n-octane/octanol/ethanol on SBA-16 silica

Autor:	Rico Rockmann, Grit Kalies
Rok vydání:	2006
Předmět:	Octanol Ethanol Analytical chemistry Alcohol Mesoporous silica Surfaces Coatings and Films Electronic Optical and Magnetic Materials Biomaterials chemistry.chemical_compound Colloid and Surface Chemistry Adsorption chemistry Organic chemistry Wetting Ternary operation Octane
Zdroj:	Journal of colloid and interface science. 315(1)
ISSN:	0021-9797
Popis:	SBA-16 silica samples with cubic I m 3 ¯ m symmetry were synthesized according to methods reported in literature and characterized by nitrogen adsorption and X-ray diffraction. The adsorption behavior of the n-octane(1)/octanol(2), n-octane(1)/ethanol(3), and octanol(2)/ethanol(3) binary liquid mixtures on SBA-16 was studied over the whole concentration range at 25 °C. Inverted U-shape isotherms were found and described by mathematical functions. The experimental binary data were verified by using a consistency test for the specific free wetting energies on the liquid/solid interface. The ternary adsorption excess isotherms of n-octane(1)/octanol(2)/ethanol(3) at 25 °C were predicted from the binary data. The work presents the first complete and consistent tabular set of binary liquid adsorption data for creating ternary data on ordered mesoporous silica.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e9074d95052fbfa9df82dbfc17f0b9d https://pubmed.ncbi.nlm.nih.gov/17631307 Zobrazit plný text záznamu Full Text from ScienceDirect