Preparation and Characterization of Porous Ti/SnO2–Sb2O3/PbO2 Electrodes for the Removal of Chloride Ions in Water
Autor: | Pan Chen, Kangdong Xu, Yunbai Luo, Jianghua Peng, Wankai Gu, Ping Yu |
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Jazyk: | angličtina |
Rok vydání: | 2019 |
Předmět: |
Materials science
Inorganic chemistry chemistry.chemical_element Bioengineering 02 engineering and technology influencing factors 010402 general chemistry Electrochemistry lcsh:Chemical technology 01 natural sciences Chloride Oxygen Ion lcsh:Chemistry electrocatalytic oxidation medicine Chemical Engineering (miscellaneous) lcsh:TP1-1185 Porosity Process Chemistry and Technology Oxygen evolution 021001 nanoscience & nanotechnology the porous electrode 0104 chemical sciences chemistry lcsh:QD1-999 Electrode chloride ions removal ratio 0210 nano-technology Current density medicine.drug |
Zdroj: | Processes, Vol 7, Iss 10, p 762 (2019) Processes Volume 7 Issue 10 |
ISSN: | 2227-9717 |
Popis: | Porous Ti/SnO2&ndash Sb2O3/PbO2 electrodes for electrocatalytic oxidation of chloride ions were studied by exploring the effects of different operating conditions, including pore size, initial concentration, current density, initial pH, electrode plate spacing, and the number of cycles. In addition, a physicochemical characterization and an electrochemical characterization of the porous Ti/SnO2&ndash Sb2O3/PbO2 electrodes were performed. The results showed that Ti/SnO2&ndash Sb2O3/PbO2 electrodes with 150 µ m pore size had the best removal effect on chloride ions with removal ratios amounting up to 98.5% when the initial concentration was 10 g L&minus 1, the current density 125 mA cm&minus 2, the initial pH = 9, and the electrode plate spacing 0.5 cm. The results, moreover, showed that the oxygen evolution potential of 150 µ m porous Ti/SnO2-Sb2O3/PbO2 electrodes was highest, which minimized side reactions involving oxygen formation and which increased the removal effect of chloride ions. |
Databáze: | OpenAIRE |
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