USE OF MEMBRANE EMULSION SPAN 80 AND TOPO IN URANIUM EXTRACTION AND STRIPPING

Autor:	Dian Puspita, Bambang E H.B, Kris Tri Basuki, Nurimaniwathy Nurimaniwathy
Rok vydání:	2017
Předmět:	Chromatography Stripping (chemistry) lcsh:T Chemistry Extraction (chemistry) chemistry.chemical_element Uranium lcsh:Technology lcsh:TK9001-9401 Membrane Emulsion lcsh:Nuclear engineering. Atomic power lcsh:Electrical engineering. Electronics. Nuclear engineering lcsh:TK1-9971 Nuclear chemistry
Zdroj:	Urania, Vol 22, Iss 3 (2017)
ISSN:	2528-0473 0852-4777
Popis:	USE OF MEMBRANE EMULSION SPAN 80 AND TOPO IN URANIUM EXTRACTION AND STRIPPING. Membrane emulsion span 80 and TOPO used in uranium extraction and stripping has been done. The extraction was carried outby emulsion membrane H 3 PO 4 in TOPO-Kerosene. The feed or external aqueous phase was uranium in HNO 3 . The emulgator span-80 was used to obtain a stable emulsion membrane system. The influence factors were percentage of TOPO-Kerosene, time extraction, molarity of external aqueous phase and molarity of internal aqueous. After the emulsion membrane was formed, the extractionand stripping process was performed. The ratio volume feed : volume membrane phase equal to 1 : 1 and volume of 5 % TOPO-Kerosene : Volume 3 M H 3 PO 4 equal 1 : 1 were used. The relative good yield were obtained at concentration of TOPO in Kerosene and 3 M H 3 PO 4 was 5 %, molarity of internal aqueous phase equal to 1 M, molarity of external aqueous phase 3 M H 3 PO 4 and time extraction equalto 10 minutes with the speed of emulsification was 8000 rpm. At this condition the extraction efficiency of uranium obtained was 97.8 %, the stripping efficiency 52.56 %, and the total efficiency was 53.80 %. Keywords : membrane emulsion, extraction, stripping, span 80, kerosene, uranium. ABSTRAK PENGGUNAAN MEMBRAN EMULSI SPAN 80 DAN TOPO UNTUK EKSTRASI DAN STRIPPING URANIUM. Telah dilakukan penelitian membran emulsi span 80 dan TOPO yang digunakan untuk ekstraksi uranium. Extraksi dengan membran emulsi H 3 PO 4 dalam TOPO-Kerosen. Larutan umpan untuk fasa air eksternal adalah uranium dalam asam nitrat. Untuk memperoleh sistem emulsi yang stabil dipakai emulgator Span 80. Parameter yang berpengaruh adalah persen TOPO-Kerosene, molaritas fasa air internal H 3 PO 4 , molaritas fasa air eksternal HNO 3 dan waktu ekstraksi. Setelah diperoleh membran emulsi, kemudian dilakukan proses ekstraksi dan stripping, dengan rasio volume umpan : volume membran sebesar 1 : 1; volume 5% TOPO-Kerose : volume 3M H 3 PO 4 sebesar 1 : 1. Hasil relatif lebih baik diperoleh pada konsen-trasi TOPO Kerosene: volume 3 M H 3 PO 4 adalah 5 %, molaritas larutan fasa internal sebesar 1 M, molaritas larutan fasa eksternal adalah 3 M H 3 PO 4 dan waktu ekstraksi sebesar 10 menit dengan kecepatan emulsi 8000 rpm. Pada kondisi ini diperoleh effisiensi ekstraksi uranium 97,8 %, efisiensi stripping 52,56 % dan efisiensi total adalah 53,8 %. Kata Kunci : membran emulsi, ekstraksi, stripping, span 80, kerosen, uranium.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e2b1755a553c622073af741d889293c https://doi.org/10.17146/urania.2016.22.3.3185 Zobrazit plný text záznamu