‘Metal Ion Electrophilic Catalysis’ in Ring-Opening Reactions of 1,2-Epoxides by Metal Halides in Ionic Liquids

Autor:	Dario Landini, Cecilia Betti, Angelamaria Maia
Rok vydání:	2006
Předmět:	Organic Chemistry General Medicine Photochemistry Ring (chemistry) Ion Catalysis Metal chemistry.chemical_compound Metal halides chemistry Nucleophile visual_art Electrophile Ionic liquid Polymer chemistry visual_art.visual_art_medium
Zdroj:	Synlett. 2006:1335-1338
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-2006-941562
Popis:	Metal ion electrophilic catalysis (Li + > Na + K + ) has been found in ring-opening reactions of 1,2-epoxides 1-5 by metal halides MHal in ionic liquids. The results have been rationalized on the basis of a transition state where the cation M + stabilizes the negative charge developing on the oxygen atom of the oxirane ring while favoring the nucleophilic attack at the adjacent carbon by the ion-paired anion Hal - .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e21aa389922a68496211f693b384ba4 https://doi.org/10.1055/s-2006-941562 Zobrazit plný text záznamu