Anion−π−π Interactions in a Dinuclear M2L2Metallocycle

Autor:	Jordi Benet-Buchholz, Pablo Ballester, Magdalena Capó
Rok vydání:	2008
Předmět:	Inorganic Chemistry Crystallography Chemistry Stereochemistry Ligand Pi Solid-state Pi interaction Physical and Theoretical Chemistry Metallacycle Ion
Zdroj:	Inorganic Chemistry. 47:10190-10192
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic801282r
Popis:	The combination of the square-planar cis-protected [Pt(dppp)(O 3SCF 3) 2] (M) with the ditopic N, N'-bis(3,5-dimethyl-4-pyridinyl)-4-ethoxy-2,6-pyridinedicarboxamide ligand (L) leads both in solution and in the solid state to the quantitative self-assembly of a M 2L 2 metallocycle. We also report crystallographic evidence derived from the solid-state structure of the dinuclear metallocycle in support of the existence of anion-pi-pi interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e1be8c6c094b9d808ccaa1089198e4c https://doi.org/10.1021/ic801282r Zobrazit plný text záznamu