Metathesis Reactions between Heavy d-8 Fluorides and I(III)-Pyridine Complexes

Autor:	Mohammad Albayer, Georgina Armendáriz-Vidales, Jason L. Dutton, Lachlan Sharp-Bucknall, Conor F. Hogan, Nilan Withanage
Rok vydání:	2020
Předmět:	010405 organic chemistry Cationic polymerization 010402 general chemistry 01 natural sciences Medicinal chemistry Redox 3. Good health 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Nucleophile chemistry Pyridine Salt metathesis reaction Physical and Theoretical Chemistry
Zdroj:	Inorganic chemistry. 59(5)
ISSN:	1520-510X
Popis:	The reaction between trans-[AuF2(pyridine)2]+ and [PhI(pyridine)2]2+ results in the formation of PhIF2 and [Au(pyridine)4]3+. Investigation of the reaction pathway using model Pd and Pt analogues of the gold complex indicate that the most likely mechanism is attack by the Au–F onto the I(III), rather than a redox process. This demonstrates that the Au(III)–F fragment can behave in a nucleophilic manner even in a relatively electron-poor cationic complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1dfe36d684399f4314a6d47969c02a66 https://pubmed.ncbi.nlm.nih.gov/32073834 Zobrazit plný text záznamu