Enantioselective Carbonyl 1,2- or 1,4-Addition Reactions of Nucleophilic Silyl and Diazo Compounds Catalyzed by the Chiral Oxazaborolidinium Ion
| Autor: | Do Hyun Ryu, Su Yong Shim |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Addition reaction
Silylation 010405 organic chemistry Enantioselective synthesis General Medicine General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Lewis acid catalysis Catalysis chemistry.chemical_compound chemistry Nucleophile Organic synthesis Diazo |
| Zdroj: | Accounts of Chemical Research. 52:2349-2360 |
| ISSN: | 1520-4898 0001-4842 |
| DOI: | 10.1021/acs.accounts.9b00279 |
| Popis: | ConspectusBoron Lewis acid catalysis has a long history and has become one of the most powerful methods for organic synthesis. In addition to achiral boron catalysts such as BX3 (X = F, Cl, Br) and... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|