Solvent-Free, Metal-Free, Aza-Prins Cyclization: Unprecedented Access to δ-Sultams
| Autor: | Damien Clarisse, Fabienne Fache, Béatrice Pelotier |
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| Přispěvatelé: | Depierre, Frédérique, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (ICBMS), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut National des Sciences Appliquées de Lyon (INSA Lyon), Université de Lyon-Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-École Supérieure Chimie Physique Électronique de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2012 |
| Předmět: |
Green chemistry
Aldehydes Aza Compounds Sulfonamides Solvent free Molecular Structure [CHIM.ORGA]Chemical Sciences/Organic chemistry 010405 organic chemistry Chemistry Organic Chemistry General Chemistry Prins reaction [CHIM.ORGA] Chemical Sciences/Organic chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Metal free Cyclization Molecule Organic chemistry [SDV.BBM.BC]Life Sciences [q-bio]/Biochemistry Molecular Biology/Biochemistry [q-bio.BM] [SDV.BBM.BC] Life Sciences [q-bio]/Biochemistry Molecular Biology/Biochemistry [q-bio.BM] |
| Zdroj: | Chemistry-A European Journal Chemistry-A European Journal, Wiley-VCH Verlag, 2013, 19 (3), pp.857-860 |
| ISSN: | 0947-6539 1521-3765 |
| DOI: | 10.1002/chem.201203415 |
| Popis: | International audience; Aza-Prins and the pauper: Aza-Prins cyclization between γ,δ-unsaturated tosylamines and aldehydes was successfully performed under solvent-free and metal-free conditions. When applied to β,γ-unsaturated sulfonamides, the corresponding δ-sultams were isolated in good yields (see scheme). This approach constitutes a new route to cyclic sulfonamides. |
| Databáze: | OpenAIRE |
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