Regioselective switching approach for the synthesis of α and δ carboline derivatives
| Autor: | Ashok Konala, Ching Fa Yao, Chun Wei Kuo, Tang Hao Yang, Veerababurao Kavala, Chia Yu Huang |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Metals and Alloys Regioselectivity General Chemistry 010402 general chemistry Oxime 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Organic chemistry |
| Zdroj: | Chemical Communications. 53:1676-1679 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c6cc09468f |
| Popis: | A metal-free protocol for accessing both α and δ-carboline derivatives, starting from a common indolylchalcone oxime ester precursor is reported. The reaction involves mild conditions and uses a regiodivergent approach. DDQ is used as a switching agent in selectively generating α and δ-carboline derivatives in good to moderate yields. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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