An unprecedented oxidative intermolecular homo coupling reaction between two sp3C–sp3C centers under metal-free condition
| Autor: | Santosh K. Sahoo |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Activation
Oxidative phosphorylation 010402 general chemistry Photochemistry 01 natural sciences Biochemistry Coupling reaction chemistry.chemical_compound Alkaloids Nickel Dibenzylic Alkanes Drug Discovery Pyridine Oxidizing agent Polymer chemistry N Bond Formation Benzylic Halides Iodine(Iii) Reagents Amination 010405 organic chemistry Chemistry Organic Halides Organic Chemistry Intermolecular force Metal Free Toluene 0104 chemical sciences Cdc Reaction Metal free Reagent Atmospheric Oxygen C-C Coupling Derivatives |
| Zdroj: | Tetrahedron Letters. 57:3476-3480 |
| ISSN: | 0040-4039 |
| Popis: | An unprecedented formation of benzylic sp(3)C-sp(3)C coupled dibenzylic products has been illustrated. The reactions have been carried out in the presence of three oxidizing reagents, i.e., diacetoxy-iodobenzene (IBDA), N-fluorobenzenesulfonimide (NFSI), and pyridine (Py) using toluene derivatives. (C) 2016 Elsevier Ltd. All rights reserved. |
| Databáze: | OpenAIRE |
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