Metallosupramolecular Ni2L3 and Ni4L6 complexes of bis-bidentate pyridine-containing ligands: X-ray structures and catalytic proton reduction

Autor:	Lingjing Chen, Lu-Wei Li, Chui-Shan Tsang, Hoi-Lun Kwong, Tai-Chu Lau, Shek-Man Yiu
Rok vydání:	2015
Předmět:	Inorganic Chemistry chemistry.chemical_compound Crystallography Denticity chemistry Proton Pyridine Supramolecular chemistry Photocatalysis Reactivity (chemistry) Photochemistry Catalysis Ion
Zdroj:	Dalton Transactions. 44:13087-13092
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c5dt01706h
Popis:	The pyridine-containing ligands L1 and L2 react with Ni2+ ions to afford dinuclear triple-stranded helicate and tetrahedral cage supramolecular complexes, respectively; the two architectures exhibit contrasting reactivity towards electro- and photocatalytic proton reduction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1cb918489767b57f67478515aa7692f2 https://doi.org/10.1039/c5dt01706h Zobrazit plný text záznamu