Rotaxane‐Like Structures Threaded through the Pores of Hollow Porous Nanocapusles

Autor:	Nasim Ehterami, Sergey A. Dergunov, Eugene Pinkhassik
Rok vydání:	2016
Předmět:	chemistry.chemical_classification Nanostructure Rotaxane 010405 organic chemistry Chemistry Organic Chemistry Nanotechnology General Chemistry Polymer 010402 general chemistry 01 natural sciences Catalysis Nanocapsules 0104 chemical sciences Nanopore Molecule Porosity Linker
Zdroj:	Chemistry – A European Journal. 22:14137-14140
ISSN:	1521-3765 0947-6539
Popis:	Nanocapsules with molecules threaded through the porous shells may lead to advanced cell-mimicking functional devices. Herein, we show the feasibility of synthesizing such hybrid nanostructures by using vesicle-templated polymer nanocapsules with controlled nanopores. Ship-in-a-bottle assembly inside a nanocapsule created an internal unit. An external unit was then connected to an entrapped internal unit through pre-attached linker threaded through a nanopore in the shell of the nanocapsule. Both internal and external units are larger than the pore size and cannot cross the shell, producing a rotaxane-like structure. Successful synthesis was achieved with fairly short linkers (six and ten carbon atoms in a chain), creating an opportunity for facile synthesis of functional devices capable of cross-shell communication.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1c26ce3df78cac7de82862d851841b42 https://doi.org/10.1002/chem.201602731 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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