catena-Poly[[[bis(3-hydroxyadamantane-1-carboxylato-κO 1)(3-hydroxyadamantane-1-carboxylic acid-κO 1)zinc(II)]-μ2-4,4′-bipyridine] monohydrate]
| Autor: | Quan-Yin Guan, Xiao-Ju Chen, Guo-Liang Zhao, Jin-Bei Shen |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
Metal-Organic Papers
Chemistry Hydrogen bond Coordination polymer Metal ions in aqueous solution Adamantane Aromaticity General Chemistry Dihedral angle Condensed Matter Physics Bioinformatics Medicinal chemistry 4 4'-Bipyridine chemistry.chemical_compound Trigonal bipyramidal molecular geometry General Materials Science |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| Popis: | In the title coordination polymer, {[Zn(C(11)H(15)O(3))(2)(C(10)H(8)N(2))(C(11)H(16)O(3))]·H(2)O}(n), the Zn(II) ion is five coordinated by two N atoms from two 4,4'-bipyridine (4,4'-bpy) mol-ecules and three O atoms from two 3-hy-droxy-adamantane-1-carboxyl-ate anions (L) and one 3-hy-droxy-adamantane-1-carb-oxy-lic acid (HL) mol-ecule. The resulting coordination polyhedron is a near regular ZnN(2)O(3) trigonal bipyramid, with the N atoms in axial sites. The 4,4'-bpy mol-ecules [dihedral angle between the aromatic rings = 17.2 (2)°] act as bridges, connecting the metal ions into an infinite polymeric chain propagating in [[Formula: see text]01]. O-H⋯O hydrogen bonds help to consolidate the packing. |
| Databáze: | OpenAIRE |
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