| Autor: |
El Mostafa Tjiou, Lhoussaine El Ghayati, Lahcen El Ammari |
| Rok vydání: |
2010 |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Structure Reports |
| ISSN: |
1600-5368 |
| DOI: |
10.1107/s1600536810000048 |
| Popis: |
In the title compound, [CuCl(C(9)H(12)N(4))(2)]Cl·0.5CH(3)OH·4H(2)O, the Cu(II) ion adopts a distorted trigonal-bipyramidal coordination arising from two bidentate ligands and a Cl(-) anion. The two heterocyclic ligands are planar with dihedral angles of 3.4 (1) and 0.7 (1)° between the pyrazole and imidazole rings. In the crystal, water mol-ecules and uncoordinated chloride anions form an O-H⋯Cl and O-H⋯O hydrogen-bonded sheet parallel to (100) which lies between two layers of complex mol-ecules. The packing is further stabilized by C-H⋯Cl and C-H⋯O hydrogen bonds. The methanol solvent mol-ecule is disordered across a centre of inversion. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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