Raman scattering and photophysics in spin-state-labile d6 metal complexes
| Autor: | John J. McGarvey, Wesley R. Browne |
|---|---|
| Přispěvatelé: | Synthetic Organic Chemistry |
| Rok vydání: | 2006 |
| Předmět: |
Spin states
spin-crossover complexes Intercalation (chemistry) resonance Raman scattering Photochemistry Artificial photosynthesis Inorganic Chemistry Metal symbols.namesake Spin crossover Materials Chemistry 3MLCT EXCITED-STATES DNA-intercalating metal complexes Physical and Theoretical Chemistry CROSSOVER COORDINATION POLYMERS Spectroscopy DIPYRIDOPHENAZINE COMPLEXES light-switch effect Chemistry LIGHT-SWITCH MECHANISM ARTIFICIAL PHOTOSYNTHESIS RESOLVED RESONANCE RAMAN ROOM-TEMPERATURE d(6) transition metal ions visual_art visual_art.visual_art_medium symbols VIBRATIONAL CONTRIBUTIONS Raman spectroscopy Raman scattering COUPLED ELECTRON-TRANSFER ENTROPY CHANGE |
| Zdroj: | Coordination Chemistry Reviews, 250(13-14), 1696-1709. Elsevier Science |
| ISSN: | 0010-8545 |
| Popis: | In this review two areas of d(6) transition metal ion chemistry and photophysics are briefly reviewed (i) that of Ru(II)dipyridophenazine (dppz) complexes as DNA intercalators and (ii) spin crossover behavior in Fe(II) complexes. In both areas the role of Raman spectroscopy in providing information concerning the spectroscopy and photophysics of the electronic states involved and the interactions between states of differing spin multiplicity is discussed. (c) 2006 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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