The origin of the particle-size-dependent selectivity in 1-butene isomerization and hydrogenation on Pd/Al2O3 catalysts
| Autor: | Günther Rupprechter, Alexander Genest, Notker Rösch, Joaquín Silvestre-Albero, Wen-Qing Li |
|---|---|
| Přispěvatelé: | Universidad de Alicante. Departamento de Química Inorgánica, Universidad de Alicante. Instituto Universitario de Materiales, Materiales Avanzados |
| Rok vydání: | 2021 |
| Předmět: |
Abundance (chemistry)
Science General Physics and Astronomy Photochemistry Particle-size-dependent selectivity Article General Biochemistry Genetics and Molecular Biology Catalysis Chemical kinetics chemistry.chemical_compound Chemical engineering Porous materials Química Inorgánica Heterogeneous catalysis Multidisciplinary Atmospheric pressure Chemistry 1-Butene 1-butene isomerization General Chemistry Hydrogenation Particle size Selectivity Pd/Al2O3 catalysts Isomerization |
| Zdroj: | Nature Communications RUA. Repositorio Institucional de la Universidad de Alicante Universidad de Alicante (UA) Nature Communications, Vol 12, Iss 1, Pp 1-8 (2021) |
| ISSN: | 2041-1723 |
| DOI: | 10.1038/s41467-021-26411-8 |
| Popis: | The selectivity of 1-butene hydrogenation/isomerization on Pd catalysts is known to be particle size dependent. Here we show that combining well-defined model catalysts, atmospheric pressure reaction kinetics, DFT calculations and microkinetic modeling enables to rationalize the particle size effect based on the abundance and the specific properties of the contributing surface facets. The selectivity of Pd catalysts in 1-butene hydrogenation and isomerization depends on nanoparticle size. Herein, the authors show by combining experiment and modeling that the type and specific properties of the contributing surface facets are decisive for the selectivity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink