A Zirconium Promenade - An Efficient Tool in Organic Synthesis
| Autor: | Anat Levin, Nicka Chinkov, Ilan Marek |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Zirconium Allylic rearrangement Double bond organic chemicals Organic Chemistry Leaving group chemistry.chemical_element food and beverages Fatty alcohol General Medicine chemistry.chemical_compound chemistry Polymer chemistry Enol ether Moiety Organic chemistry Organic synthesis Isomerization |
| Zdroj: | Synlett. :0501-0514 |
| ISSN: | 1437-2096 0936-5214 |
| DOI: | 10.1055/s-2006-932483 |
| Popis: | The one-pot preparation of allyl- and dienyl-zirconocene derivatives can be easily achieved via a tandem allylic C-H-activation-β-elimination reaction from unsaturated fatty alcohol and enol ether derivatives, respectively. The reaction proceeds rapidly, under mild conditions, and is insensitive to the length of the carbon tether between the double bond and the leaving group moiety. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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