Synthesis and characterization of alkyd resin based on soybean oil and glycerin using zirconium octoate as catalyst
| Autor: | Ramadan E. Ashery, Elsayed M. Abdel Rehim, Mohamed E. Elba |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Engineering
Chemical food.ingredient Condensation polymer Materials science One-pot synthesis Phthalic anhydride soybean oil zirconium ocotate alkyd resin chemistry.chemical_element 02 engineering and technology Raw material 010402 general chemistry 01 natural sciences Mühendislik Kimya Soybean oil chemistry.chemical_compound food Phthalic anhydride Chemical resistance Zirconium Alkyd General Medicine 021001 nanoscience & nanotechnology 0104 chemical sciences chemistry visual_art visual_art.visual_art_medium 0210 nano-technology Nuclear chemistry |
| Zdroj: | Volume: 2, Issue: 1 34-43 International Journal of Chemistry and Technology |
| ISSN: | 2602-277X |
| DOI: | 10.32571/ijct.347670 |
| Popis: | A one pot synthesis of alkyd resins based on the soybean oil and glycerin with the zirconium octoate (zirconium 2-ethyl hexanoate) as a new renewable raw material was performed. The alcoholysis reaction of soybean oil and glycerin carried out in absence of nitrogen gas inlet in the presence of zirconium octoate. The alkyd resin was obtained from polycondensation of the alcoholysis products with phthalic anhydrid at 250 °C. The structure confirmed by FT-IR and H1-NMR spectroscopy. Flexibility, drying time, hardness, adhesion test, impact resistance, gloss test and chemical resistance of synthesized alkyd resins was invesitigated. The prepared resin was formulated in white lacqure and yellowing resistance tested with commercial resins. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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