Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms
| Autor: | Stephen Hanessian, Stéphane Dorich, Daniel Tao, Kyle B. Schenthal, Martin Büschleb, Larry E. Overman |
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| Rok vydání: | 2016 |
| Předmět: |
quaternary carbon atoms
Biological Products 010405 organic chemistry Chemistry Stereochemistry natural products Organic Chemistry Total synthesis chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Article Catalysis Natural (archaeology) Carbon 0104 chemical sciences Stereocenter Biomimetic synthesis Chemical Sciences synthetic methods Organic chemistry biomimetic synthesis Quaternary carbon |
| Zdroj: | Angewandte Chemie (International ed. in English), vol 55, iss 13 Büschleb, Martin; Dorich, Stéphane; Hanessian, Stephen; Tao, Daniel; Schenthal, Kyle B; & Overman, Larry E. (2016). Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms.. Angewandte Chemie (International ed. in English), 55(13), 4156-4186. doi: 10.1002/anie.201507549. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/7rq1s17n |
| Popis: | Strategies for the total synthesis of complex natural products that contain two or more contiguous stereogenic quarternary carbon atoms in their intricate structures are reviewed with twelve representative examples. Emphasis has been put on the methods to create quarternary carbon stereocenters, including syntheses of the same natural product from different groups, thereby showcasing diversity of thought and individual creativity. A compendium of selected natural products containing two or more contiguous stereogenic quarternary carbon atoms and key reactions in their total or partial syntheses is provided in the Supporting Information section. |
| Databáze: | OpenAIRE |
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