The Major Influences of Substituent Size and Position of 3,4-Propylenedioxythiophene on the Formation of Highly Hydrophobic Nanofibers

Autor:	Thierry Darmanin, Claudio Mortier, Frédéric Guittard
Přispěvatelé:	Surfaces & Interfaces, Laboratoire de physique de la matière condensée (LPMC), Centre National de la Recherche Scientifique (CNRS)-Université Nice Sophia Antipolis (... - 2019) (UNS), COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)-COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)-Centre National de la Recherche Scientifique (CNRS)-Université Nice Sophia Antipolis (... - 2019) (UNS), COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)-COMUE Université Côte d'Azur (2015-2019) (COMUE UCA)
Rok vydání:	2014
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Nanostructure chemistry Chemical engineering Position (vector) Nanofiber Polymer chemistry Substituent [CHIM.MATE]Chemical Sciences/Material chemistry General Chemistry Polymer Isopropyl
Zdroj:	ChemPlusChem ChemPlusChem, Wiley, 2014, 79, pp.1434-1439. ⟨10.1002/cplu.201402187⟩
ISSN:	2192-6506
Popis:	International audience; We report the influence of the substituent size and position of 3,4-propylenedioxythiophene on the surface properties of the corresponding electrodeposited polymer films. We study the influence on the formation of hydrophobic nanofibers using two substituents (isopropyl and tert-butyl). We show that the 3-position of ProDOT is the best for the formation of nanofibers, because it leads to the longest polymer chains while leading to the highest intrinsic hydrophobicity; two effects increasing the formation of surface structures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19c945dee0526628480e966eb44cc3ab https://doi.org/10.1002/cplu.201402187 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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