Direct determination of the rate coefficient for the reaction of O(1D) with OCS

Autor:	Hiroshi Kohguchi, Kenichi Orimi, Katsuyoshi Yamasaki, Shinji Watanabe
Rok vydání:	2009
Předmět:	Pulsed laser Chemistry Excited state Analytical chemistry General Physics and Astronomy Irradiation Physical and Theoretical Chemistry Pressure dependence Fluorescence D-1
Zdroj:	Chemical Physics Letters. 483:16-20
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2009.10.033
Popis:	A gaseous mixture of O-3/OCS/He was irradiated at 266 nm with a pulsed laser, and vibrationally excited SO(X-3 Sigma, v = 8 and 19) generated in the reaction of O(D-1) with OCS was detected with the laser-induced fluorescence (LIF) via the B-3 Sigma -X-3 Sigma system. The apparent production rates of SO(v = 8) in the initial reaction time and their OCS pressure dependence have been measured, giving the absolute overall rate coefficient for the O(D-1) + OCS reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19b4a4d325ae9acdcb4a157e4721a4e7 https://doi.org/10.1016/j.cplett.2009.10.033 Zobrazit plný text záznamu Full Text from ScienceDirect