Synthesis of TEMPO radical decorated hollow porous aromatic frameworks for selective oxidation of alcohols
| Autor: | Hui-Ling Mao, Hu Cheng, Zhi-Wei Sui, Zhuo Chen, Yun Xue, Xiu-Jun Yu, Yan-Ming Shen, Jin-Liang Zhuang, Mi Yan, Shao-Bin Zhu |
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| Rok vydání: | 2021 |
| Předmět: |
Chemistry
Metals and Alloys High density General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Monomer Template Alcohol oxidation Polymer chemistry Materials Chemistry Ceramics and Composites Porosity Selectivity Mesoporous material Layer (electronics) |
| Zdroj: | Chemical Communications. 57:907-910 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | A bottom-up approach was developed to prepare TEMPO radical decorated hollow aromatic frameworks (HPAF-TEMPO) by using TEMPO radical functionalized monomers and SiO2 nanospheres as templates. The accessible inner layer, high density of TEMPO sites, and hybrid micro-/mesopores of the HPAF-TEMPO enable the aerobic oxidation of a broad range of alcohols with high efficiency and excellent selectivity. |
| Databáze: | OpenAIRE |
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