NaH-mediated direct C–H arylation in the presence of 1,10-phenanthroline
| Autor: | Kanako Nozawa-Kumada, Yoshinori Kondo, Masanori Shigeno, Yuki Iwakawa, So Onuma |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Trifluoromethyl
Phenanthroline Metals and Alloys General Chemistry Medicinal chemistry Chloride Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Coupling (electronics) chemistry.chemical_compound chemistry Bromide Amide Halogen Materials Chemistry Ceramics and Composites medicine Fluoride medicine.drug |
| Zdroj: | Chemical Communications. 56:7773-7776 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Transition-metal-free coupling of haloarenes with unactivated arenes has been developed in the presence of NaH and 1,10-phenanthroline. Various haloarenes bearing methyl, methoxy, halogen (fluoride, chloride, and bromide), cyano, trifluoromethyl, ester, and amide groups can be cross-coupled with unactivated arenes, or heteroarenes in this reaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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