Selective N,O-Addition of the TEMPO Radical to Conjugated Boryldienes
| Autor: | Armido Studer, Matthias Tesch, Constantin G. Daniliuc, Fatma Türkyilmaz, Gerald Kehr, Gerhard Erker, Jun Li |
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| Rok vydání: | 2015 |
| Předmět: |
Nitroxide mediated radical polymerization
010405 organic chemistry Chemistry Radical General Medicine General Chemistry Bond formation Borane Conjugated system 010402 general chemistry Photochemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound Lewis acids and bases |
| Zdroj: | Angewandte Chemie International Edition. 55:1470-1473 |
| ISSN: | 1433-7851 |
| DOI: | 10.1002/anie.201509114 |
| Popis: | B(C6F5)2-containing boryldienes 4 underwent the addition of two molar equivalents of TEMPO to give N,O-bonded four-membered heterocyclic products 7. The reaction is a metal-free example of the generation of reactive nitrogen-centered TEMPO radical derivatives, in this case by the addition of TEMPO to the borane, followed by carbon-nitrogen bond formation and subsequent trapping of the resulting allyl radical by the second equivalent of TEMPO. |
| Databáze: | OpenAIRE |
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