Construction of the Multidecker Anthracene−Silver(I) System by Intramolecular π−π Interactions

Autor:	Tetsuhiro Ohta, Hisashi Konaka, Yusaku Suenaga, Takayoshi Kuroda-Sowa, Megumu Munakata, Liang Ping Wu, Masahiko Maekawa
Rok vydání:	2003
Předmět:	Inorganic Chemistry Anthracene chemistry.chemical_compound chemistry Ligand Stereochemistry Intramolecular force Pi Pi interaction Crystal structure Physical and Theoretical Chemistry Medicinal chemistry Ion
Zdroj:	Inorganic Chemistry. 42:2553-2558
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic020379l
Popis:	As a continuation of the study on the construction of the multidecker aromatic compounds with pi-pi interactions, the anthracene derivatives 9,10-dimethylanthracene (dman), 9,10-diphenylanthracene (dpan), and 7,12-dimethylbenz[a]anthracene (dmban) have been studied toward complexation with the silver(I) ion. The crystal structures of [Ag(dman)(0.5)(p-xylene)(ClO(4))], [Ag(2)(dpan)(0.5)(C(6)H(6))(0.5)(CF(3)SO(3))(2)], and [Ag(2)(dmban)(2)(ClO(4))(2)](p-xylene), together with the metal-free ligand dpan, have been determined by single-crystal X-ray diffraction. These pi-electron-rich aromatic compounds are found to have great promise as an approach to the effective self-assembly of high nuclearity in a multilayer fashion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1926a8f1b5e4ef4416b64c5bb67006df https://doi.org/10.1021/ic020379l Zobrazit plný text záznamu