Sulfur Isotopic Exchange Between Two Thiophosphoryl Compounds

Autor:	W. Reimschüssel, J. Rudziński
Rok vydání:	1990
Předmět:	Inorganic Chemistry Chemistry Reagent Organic Chemistry Kinetics Organic chemistry Moiety chemistry.chemical_element Biochemistry Sulfur
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 51:197-197
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509008040731
Popis:	Thiophosphoryl compounds are useful sulfur donors in thionation reactions (1,2) leading to P=S –> P=O exchange in thiation reagents. Although the reverse conversions P=O –> P=S are also known, mechanisms of both these types of reactions are not thoroughly studied. The analogy of chemical and isotopic exchange reactions in thiophosphoryl moiety push us to investigate the kinetics of isotopic exchange between two thiophosphoryl compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1913b1da79b117d6f0a754c10f246dd9 https://doi.org/10.1080/10426509008040731 Zobrazit plný text záznamu