TLC of p-Nitroanilines and Their Analogues with Cyclodextrins in the Mobile Phase
| Autor: | Kathleen T. Crago, Tiffany Hollin, Michael Young, Ieva R. Politzer |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
chemistry.chemical_classification
Cyclodextrins Aniline Compounds Aqueous solution Chromatography Molecular Structure Cyclodextrin Silica gel technology industry and agriculture General Medicine Thin-layer chromatography Analytical Chemistry Inclusion compound carbohydrates (lipids) chemistry.chemical_compound chemistry Stability constants of complexes Phase (matter) Polyamide polycyclic compounds Urea Chromatography Thin Layer |
| Zdroj: | Journal of Chromatographic Science. 33:316-320 |
| ISSN: | 1945-239X 0021-9665 |
| DOI: | 10.1093/chromsci/33.6.316 |
| Popis: | The addition of alpha-, beta-, gamma-, and hydroxypropyl-beta-cyclodextrins to aqueous mobile phases can be used to enhance the migration of p-nitroanilines and their analogues on thin-layer chromatography. Urea, which is used to solubilize the cyclodextrins in aqueous solutions, is also found to increase the migration of these compounds. The equilibrium binding constants for the solute-cyclodextrin complexes formed in the mobile phase are determined. The results obtained using either silica gel or polyamide plates are similar. |
| Databáze: | OpenAIRE |
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