Extraction of uranyl nitrate, sulphate and chloride with tri-n-octyl amine (TOA) from aqueous solutions
| Autor: | J. J. Čomor, M Djordje Petkovic |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2001 |
| Předmět: |
Inorganic chemistry
02 engineering and technology uranyl chloride 010403 inorganic & nuclear chemistry 01 natural sciences Chloride lcsh:Chemistry chemistry.chemical_compound 020401 chemical engineering uranyl sulphate medicine 0204 chemical engineering Benzene Equilibrium constant Aqueous solution Extraction (chemistry) extraction equilibria General Chemistry Uranyl 0104 chemical sciences chemistry Uranyl nitrate lcsh:QD1-999 uranyl nitrate tri-n-octyl amine Amine gas treating medicine.drug Nuclear chemistry |
| Zdroj: | Journal of the Serbian Chemical Society, Vol 66, Iss 7, Pp 443-449 (2001) Journal of the Serbian Chemical Society |
| ISSN: | 1820-7421 0352-5139 |
| Popis: | Extraction of uranyl nitrate, chloride and sulphate with tri-n-octyl amine (TOA) in benzene as a function of the TOA concentration has been studied. The concentration based extraction equilibrium constants were calculated from the distribution data of the uranyl salts, fitting the parameters of a chemical model to the experimentally obtained extraction isotherms. The calculated equilibrium constants are 46.5, 89.4 and 4.2x104 for uranyl nitrate, chloride and sulphate, respectively. These values are in good agreement with the previously reported extraction equilibrium constants calculated by the inflection point method. |
| Databáze: | OpenAIRE |
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