Synthesis and reactions of beta-diketiminato divanadium(I) inverted-sandwich complexes

Autor:	Shin-An Chen, Kuan-Ming Lin, Po-Yang Wang, Yi-Chou Tsai, Jin-Ming Chen
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Chemistry Materials Chemistry Metals and Alloys Ceramics and Composites NacNac General Chemistry Photochemistry Medicinal chemistry Toluene Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications (Cambridge, England). (2)
ISSN:	1359-7345
Popis:	Reduction of VCl(2)(Nacnac) (Nacnac = HC(C(Me)NC(6)H(3)-iPr(2))(2)) with KC(8) in toluene leads to the formation of a toluene-bridged inverted-sandwich divanadium(I) complex, (mu-eta(6):eta(6)-C(7)H(8))[V(Nacnac)](2), which behaves as a source of V(Nacnac) and a multi-electron reductant in the two reactions studied in this report.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::18966c9c0e28b93d999d9d0a47147aee https://pubmed.ncbi.nlm.nih.gov/18092088 Zobrazit plný text záznamu