Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene

Autor:	Vincent J. Chebny, Rajendra Rathore, Dwairath Dhar, Sergey V. Lindeman
Rok vydání:	2006
Předmět:	animal structures Organic Chemistry Electron donor Electron Photochemistry Biochemistry Crystallography chemistry.chemical_compound Ferrocene chemistry Physical and Theoretical Chemistry Benzene Constant (mathematics) Hexaphenylbenzene
Zdroj:	Organic Letters. 8:5041-5044
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol061904d
Popis:	A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller of the hexaphenylbenzene core. The molecular structure of 5 is confirmed by X-ray crystallography. An electrochemical analysis along with redox titrations (which are tantamount to coulometry) confirmed that it ejects six electrons at a single potential. [structure: see text]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::181f43d2b7f37057ed1dc4520f76eed1 https://doi.org/10.1021/ol061904d Zobrazit plný text záznamu