Electrochemical kinetics of gold electrodes in SCN−/dimethylsulfoxide solutions

Autor:	María Elisa Martins, Alfredo J. Calandra, Carlos E. Castellano, Alejandro Jorge Arvia
Jazyk:	angličtina
Rok vydání:	1978
Předmět:	Electrochemical behaviour SCN−/dimethylsulfoxide solutions Chemistry TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY Inorganic chemistry Kinetics Electrode Electrochemical kinetics Química Gold Electrochemistry Ciencias Exactas
Zdroj:	SEDICI (UNLP) Universidad Nacional de La Plata instacron:UNLP
Popis:	The electrochemical behaviour of the Au/SCN− (DMSO) interface is studied at 25°C≤T≤65°C, by means of the triangular potential sweep technique and the RDE. Within a relatively limited potential range the main electrode process is: 3 SCN−=(SCN)3−+2e The kinetics of this reaction involves a mixed control. At higher potentials the electrodissolution of the base metal takes place. Side reactions occurring there make the overall process rather complex. The electrochemical behaviours of the Au/SCN− (DMSO) and Au/SCN− (ACN) are compared. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::180efba33e472dffadd428405afe3349 http://sedici.unlp.edu.ar/handle/10915/119485 Zobrazit plný text záznamu