An empirical equation for temperature and pressure dependence of liquid heat capacity
Autor: | Dušan K. Grozdanić, Andjela B. Knežević-Stevanović, Jovan D. Jovanović |
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Rok vydání: | 2009 |
Předmět: |
Empirical equations
Heat capacity Liquid Chemistry General Chemical Engineering Thermodynamics 02 engineering and technology General Chemistry Function (mathematics) 010402 general chemistry 01 natural sciences Correlation 0104 chemical sciences High pressure Temperature and pressure 020401 chemical engineering 0204 chemical engineering Goff–Gratch equation Model |
Zdroj: | Journal of the Taiwan Institute of Chemical Engineers |
ISSN: | 1876-1070 |
Popis: | A new empirical equation for liquid heat capacity calculation, as a function of temperature and pressure is recommended. This four-parameter equation was tested and compared to the four-parameter equation developed by Guseinov et al. (1988), five-parameter equation developed by Garg et al. (1993) and nine-parameter equation developed by Nakagawa et al. (1993), using 73 sets with 4395 literature experimental heat capacity data for 46 chemical compounds. The obtained results indicate that the proposed four-parameter equation gives in many cases better results than the tested four- and five-parameter equations and in few cases even better than the nine-parameter equation. |
Databáze: | OpenAIRE |
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