'Open Rather than Closed' Malonate Methano-Fullerene Derivatives. The Formation of Methanofulleroid Adducts of Y3N@C80

Autor:	Olena Lukoyanova, Claudia M. Cardona, Christopher J. Chancellor, A. L. Balch, Josep M. Poblet, José Rivera, Antonio Rodríguez-Fortea, Luis Echegoyen, † Leyda Z. Lugo-Morales, Marilyn M. Olmstead
Rok vydání:	2007
Předmět:	Fullerene derivatives Stereochemistry Chemistry General Chemistry Carbon-13 NMR Electrochemistry Biochemistry Catalysis Cycloaddition Adduct chemistry.chemical_compound Colloid and Surface Chemistry Malonate Proton NMR Density functional theory
Zdroj:	Journal of the American Chemical Society. 129:10423-10430
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja071733n
Popis:	Cycloaddition of bromomalonates to Y3N@C80 unexpectedly gave rise to fulleroid derivatives with unusually high stability. Complete characterization of these derivatives is described including X-ray crystallography, 1H NMR, 13C NMR, HMQC, UV-visible, HPLC, MALDI-MS, and electrochemistry. Density functional theory calculations are also presented, which provide a rationale for the formation of the fulleroid and reveal the underlying thermodynamic basis for their stability.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::17982093e76391cda511ef90fa10404a https://doi.org/10.1021/ja071733n Zobrazit plný text záznamu