Discovery and properties of a new indigoid structure type based on dimeric cis-indigos
| Autor: | Corey A. Sanz, Cassidy M. Conover, Robin G. Hicks, Hyejin Hong, Dillon T. Hofsommer |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Indole test
010405 organic chemistry Chemistry Organic Chemistry 010402 general chemistry 01 natural sciences Biochemistry Redox Indigo 0104 chemical sciences 3. Good health Quinone Sodium hydride chemistry.chemical_compound Ultraviolet visible spectroscopy Polymer chemistry X-ray crystallography Physical and Theoretical Chemistry Cis–trans isomerism |
| Zdroj: | Organic & Biomolecular Chemistry. 18:5838-5842 |
| ISSN: | 1477-0539 1477-0520 |
| DOI: | 10.1039/d0ob01368d |
| Popis: | Reactions of indigo with quinones in the presence of sodium hydride leads unexpectedly to products containing two indigo subunits; one indigo is featured in a cis configuration and fused via its indole nitrogen atoms to a second indigo at the central C-C bond of the latter. Structural, optical, and redox properties of the new compounds are reported. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|