Trace water affects tris(pentafluorophenyl)borane catalytic activity in the Piers–Rubinsztajn reaction
| Autor: | Alyssa F. Schneider, Yang Chen, Michael A. Brook |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Depolymerization Inorganic chemistry Borane 010402 general chemistry 7. Clean energy 01 natural sciences Silicone oil 0104 chemical sciences Catalysis Inorganic Chemistry Reaction rate chemistry.chemical_compound chemistry 13. Climate action Reagent Siloxane Tris(pentafluorophenyl)borane |
| Zdroj: | Dalton Transactions. 48:13599-13606 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c9dt02756d |
| Popis: | Improved methods to control silicone synthesis are required due to the sensitivity of siloxane bonds to acid/base-mediated chain redistribution/depolymerization. The Piers-Rubinsztajn reaction employs tris(pentafluorophenyl)borane as an efficient catalyst ( |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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