Charge transfer complexes and cation radical salts of azino-diselenadiazafulvalene
| Autor: | Alenka Majcen Le Marechal, L. Piekara-Sady, Zdenko Časar, Dominique Lorcy, Ivan Leban |
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| Přispěvatelé: | Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), University of Ljublajana, University of Maribor, Institute of Molecular Physics, Polska Akademia Nauk = Polish Academy of Sciences (PAN), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), University of Ljubljana |
| Rok vydání: | 2009 |
| Předmět: |
[CHIM.ORGA]Chemical Sciences/Organic chemistry
010405 organic chemistry General Chemical Engineering Inorganic chemistry Charge (physics) General Chemistry Crystal structure 010402 general chemistry Electrochemistry 01 natural sciences Redox 0104 chemical sciences chemistry.chemical_compound chemistry Radical ion Polymer chemistry Moiety Molecule Thiazole ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Comptes Rendus. Chimie Comptes Rendus. Chimie, Académie des sciences (Paris), 2009, pp.1057-1065. ⟨10.1016/j.crci.2008.08.013⟩ Comptes Rendus. Chimie, 2009, pp.1057-1065. ⟨10.1016/j.crci.2008.08.013⟩ |
| ISSN: | 1631-0748 1878-1543 |
| DOI: | 10.1016/j.crci.2008.08.013 |
| Popis: | The synthesis and the redox behaviour of electroactive donor molecules incorporating an azino spacer group between a benzoselenazole core and another heterocyclic moiety, either a benzoselenazole one or a thiazole one, are reported. Neutral complexes were obtained with TCNQ and, for the first time with dithiadiazafulvalene or diselenadiazafulvalene derivatives, cation radical salts by electrocrystallization. Crystal structures data of these complexes are presented and their geometries compared with those deduced from theoretical calculations. |
| Databáze: | OpenAIRE |
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