[OSSO]-bisphenolate metal complexes: A powerful and versatile tool in polymerization catalysis
| Autor: | David Hermann Lamparelli, Veronica Paradiso, Carmine Capacchione, Vito Capaccio |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
010405 organic chemistry
Homogeneous catalysis 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Styrene Catalysis Inorganic Chemistry Metal chemistry.chemical_compound Stereospecificity Monomer chemistry Polymerization visual_art Materials Chemistry visual_art.visual_art_medium Green building Physical and Theoretical Chemistry |
| Zdroj: | Coordination Chemistry Reviews. 429:213644 |
| ISSN: | 0010-8545 |
| DOI: | 10.1016/j.ccr.2020.213644 |
| Popis: | Since the report of the stereospecific polymerization of styrene dated 2003, metal complexes bearing [OSSO]-bisphenolate ligands have been successfully applied in different branches of homogeneous catalysis, de facto building a new research field. This review will focus on polymerization reactions promoted by these complexes, starting with those involving “traditional” monomers (such as fossil-derived olefins) up to more recent and green applications, like polymerization of terpenes or utilization of CO2 as a green building block. |
| Databáze: | OpenAIRE |
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