Graphene Nanoribbons as an Advanced Precursor for Making Carbon Fiber
| Autor: | Chih-Chau Hwang, Natnael Behabtu, Jay R. Lomeda, Chenguang Zhang, Satish Kumar, Changsheng Xiang, Yaodong Liu, Han Gi Chae, Colin C. Young, Dmitry V. Kosynkin, Matteo Pasquali, Bostjan Genorio, James M. Tour, Dmitri E. Tsentalovich |
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| Rok vydání: | 2013 |
| Předmět: |
Models
Molecular Hot Temperature Materials science Annealing (metallurgy) Molecular Conformation Oxide General Physics and Astronomy law.invention chemistry.chemical_compound Colloid Carbon Fiber law Liquid crystal Ultimate tensile strength General Materials Science Composite material Spinning Nanotubes Carbon Graphene Electric Conductivity General Engineering Carbon Liquid Crystals Solubility chemistry Graphite Graphene nanoribbons |
| Zdroj: | ACS Nano. 7:1628-1637 |
| ISSN: | 1936-086X 1936-0851 |
| DOI: | 10.1021/nn305506s |
| Popis: | Graphene oxide nanoribbons (GONRs) and chemically reduced graphene nanoribbons (crGNRs) were dispersed at high concentrations in chlorosulfonic acid to form anisotropic liquid crystal phases. The liquid crystal solutions were spun directly into hundreds of meters of continuous macroscopic fibers. The relationship of fiber morphology to coagulation bath conditions was studied. The effects of colloid concentration, annealing temperature, spinning air gap, and pretension during annealing on the fibers' performance were also investigated. Heat treatment of the as-spun GONR fibers at 1500 °C produced thermally reduced graphene nanoribbon (trGNR) fibers with a tensile strength of 378 MPa, Young's modulus of 36.2 GPa, and electrical conductivity of 285 S/cm, which is considerably higher than that in other reported graphene-derived fibers. This better trGNR fiber performance was due to the air gap spinning and annealing with pretension that produced higher molecular alignment within the fibers, as determined by X-ray diffraction and scanning electron microscopy. The specific modulus of trGNR fibers is higher than that of the commercial general purpose carbon fibers and commonly used metals such as Al, Cu, and steel. The properties of trGNR fibers can be further improved by optimizing the spinning conditions with higher draw ratio, annealing conditions with higher pretensions, and using longer flake GONRs. This technique is a new high-carbon-yield approach to make the next generation carbon fibers based on solution-based liquid crystal phase spinning. |
| Databáze: | OpenAIRE |
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