Caprolactam from renewable resources: Catalytic conversion of 5‐hydroxymethylfurfural into caprolactone
| Autor: | Ignacio Melián-Cabrera, Sébastien Noël, Johannes G. de Vries, Hero J. Heeres, Pim Huat Phua, Teddy Buntara |
|---|---|
| Přispěvatelé: | UCCS Équipe Catalyse Supramoléculaire, Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille-Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Synthetic Organic Chemistry, Chemical Technology, Stratingh Institute of Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
Green chemistry
OXYGENATED HYDROCARBONS FUELS PHASE hydroxymethylfurfural DIOLS 010402 general chemistry 7. Clean energy 01 natural sciences Catalysis CHEMICALS chemistry.chemical_compound FRUCTOSE DEHYDRATION Organic chemistry [CHIM]Chemical Sciences Furaldehyde sustainable chemistry Caproates GeneralLiterature_REFERENCE(e.g. dictionaries encyclopedias glossaries) ComputingMilieux_MISCELLANEOUS caprolactone biomass business.industry 010405 organic chemistry LACTONES Caprolactam General Chemistry General Medicine caprolactam TRANSFORMATION Renewable energy 0104 chemical sciences chemistry business Selectivity Caprolactone Hydroxymethylfurfural Renewable resource |
| Zdroj: | Angewandte Chemie International Edition Angewandte Chemie International Edition, Wiley-VCH Verlag, 2011, 50 (31), pp.7083-7087. ⟨10.1002/anie.201102156⟩ Angewandte Chemie International Edition, 2011, 50 (31), pp.7083-7087. ⟨10.1002/anie.201102156⟩ Angewandte Chemie-International Edition, 50(31), 7083-7087. WILEY-V C H VERLAG GMBH |
| ISSN: | 1433-7851 1521-3773 |
| DOI: | 10.1002/anie.201102156⟩ |
| Popis: | Renewable nylon: 5-Hydroxymethylfurfural (HMF), which can be obtained from renewable resources such as D-fructose, was converted into caprolactone with very good overall selectivity in only three steps. The new route involves two hydrogenation steps to obtain 1,6-hexanediol, which was oxidatively cyclized to caprolactone, and then converted into caprolactam. |
| Databáze: | OpenAIRE |
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