Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine
| Autor: | Nariman F. Salakhutdinov, V. V. Fomenko, Sergey S. Laev |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Monoterpene
Epoxide Turpentine lcsh:Chemical technology 010402 general chemistry 01 natural sciences Catalysis lcsh:Chemistry chemistry.chemical_compound 3-carene epoxide epoxidation Organic chemistry lcsh:TP1-1185 Physical and Theoretical Chemistry Hydrogen peroxide Limonene Pinene 010405 organic chemistry Carene aqueous hydrogen peroxide 3-carene limonene diepoxide 0104 chemical sciences α-pinene epoxide lcsh:QD1-999 chemistry α-pinene limonene turpentine |
| Zdroj: | Catalysts Volume 11 Issue 4 Catalysts, Vol 11, Iss 436, p 436 (2021) |
| ISSN: | 2073-4344 |
| DOI: | 10.3390/catal11040436 |
| Popis: | The epoxidation of turpentine (technical α-pinene), 3-carene, and limonene with aqueous hydrogen peroxide was studied in a new catalytic system employing manganese sulfate, salicylic acid, sodium bicarbonate, and acetonitrile, as a polar solvent. The proposed approach makes it possible to carry out a “chemical separation” of turpentine components, yielding valuable individual derivatives of monoterpenes without the need to isolate individual monoterpene reagents. Specific methods have been developed for the production of α-pinene epoxide, 3-carene epoxide, limonene diepoxide, as well as for two related compounds: 3-carene-5-one and 3-carene-2,5-dione. |
| Databáze: | OpenAIRE |
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